Orbital Angular Momentum Operator Lx in Spherical Coordinates | Quantum Science Philippines
Quantum Science Philippines

Orbital Angular Momentum Operator Lx in Spherical Coordinates

by Alvin P. Aballe, MSU-IIT

Orbital angular momentum, including the total and spin angular momentum, plays a significant part in both classical and quantum mechanics. In classical mechanics, this is one of the conserve quantities alongside energy and linear momentum. With this, one can easily deal systems undergoing rotations. With that in mind, this will also be significant in dealing with the structure of the atom.

Like any other operators in quantum mechanics (position and linear momentum operator), orbital angular momentum as an operator could be expressed in different coordinate systems. The conversion of orbital angular momentum from one coordinate system to another could be convenient and efficient depending on the geometry of the system. So, given a system of spherical geometry, it is convenient to use the spherical form of this operator.

In 3D cartesian coordinate system, \overset{\rightharpoonup}{L}(x, y, z) = ( L_x \hat x, L_y \hat y, L_z \hat z).

In this article, we will express the x-component from cartesian to spherical coordinates.

 

Solution:

In classical mechanics,

\overset{\rightharpoonup} L = \overset{\rightharpoonup}r \times \overset{\rightharpoonup}p.

By replacing \overset{\rightharpoonup}L, \overset{\rightharpoonup}r, and \overset{\rightharpoonup}p with their operator counterparts, we can obtain the quantum mechanical orbital angular momentum operator which is

\overset{\rightharpoonup} L = \overset{\rightharpoonup}r \times \overset{\rightharpoonup}p

where \overset{\rightharpoonup}p = -i\hbar\overset{\rightharpoonup}\nabla.

So,

\begin{array}{lll} \overset{\rightharpoonup}L & = & \overset{\rightharpoonup}r \times (-i\hbar\overset{\rightharpoonup}\nabla) \\ & = & -i\hbar (\overset{\rightharpoonup}r \times \overset{\rightharpoonup}\nabla) \end{array}

\Rightarrow \overset{\rightharpoonup}L = -i\hbar \begin{array}{ |ccc|} \hat r & \hat\theta & \hat\phi \\ r & 0 & 0\\ \frac{\partial}{\partial r} & \frac{1}{r}\frac{\partial}{\partial\theta} & \frac{1}{r\sin\theta}\frac{\partial}{\partial\phi}\end{array}

\begin{array}{lll}\Rightarrow\overset{\rightharpoonup}L & = & -i\hbar (0\hat r - \frac{1}{\sin\theta}\frac{\partial}{\partial\phi}\hat\theta + \frac{\partial}{\partial\theta} \hat\phi)\\ & = & -i\hbar (\frac{\partial}{\partial\theta}\hat\phi - \frac{1}{\sin\theta}\frac{\partial}{\partial\phi}\hat\theta). \end{array}

Recall that

\begin{array}{lll} \hat x & = & \sin\theta\cos\phi\hat r -\sin\phi\hat\phi + \cos\theta\cos\phi\hat\theta\\ \hat y & = & \sin\theta\sin\phi\hat r + \cos\phi\hat\phi + \cos\theta\sin\phi\hat\theta\\ \hat z & = & \cos\theta\hat r - \sin\theta \hat\theta.\end{array}

 

Now, if we take the dot product of \overset{\rightharpoonup}L and \hat x or \overset{\rightharpoonup}L \cdot \hat x, we will eventually obtain expression for L_x.

So,

\begin{array}{lll} \overset{\rightharpoonup}L \cdot \hat x & = & -i\hbar (\frac{\partial}{\partial\theta}\hat\phi - \frac{1}{\sin\theta}\frac{\partial}{\partial\phi}\hat\theta) \cdot (\sin\theta\cos\phi\hat r - \sin\phi\hat\phi + \cos\theta\cos\phi\hat\theta)\\ & = & -i\hbar ((-\sin\phi)\frac{\partial}{\partial\theta} - (\cos\theta\cos\phi)\frac{1}{\sin\theta}\frac{\partial}{\partial\phi})\\ & = & i\hbar (\sin\phi\frac{\partial}{\partial\theta} + \frac{\cos\theta\cos\phi}{\sin\theta}\frac{\partial}{\partial\phi})\\ L_x & = & i\hbar (\sin\phi\frac{\partial}{\partial\theta} + \frac{\cos\phi}{\tan\theta}\frac{\partial}{\partial\phi}). \end{array}

And thus, we successfully expressed orbital angular momentum operator x-component in spherical coordinates.

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