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	<title>Quantum Science Philippines &#187; Quantum Oscillators</title>
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		<title>Perturbation Theory: Quantum Oscillator Problem</title>
		<link>http://www.quantumsciencephilippines.com/345/perturbation-theory-quantum-oscillator-problem/</link>
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		<pubDate>Mon, 20 Apr 2009 11:13:45 +0000</pubDate>
		<dc:creator>Ancelie C. Rosales</dc:creator>
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by ANCELIE C. ROSALES

// --&#62;

In quantum mechanics, the perturbation theory is a very important mathematical tool which is used to approximate physical quantities that describe complicated quantum systems based on our knowledge on the simpler ones. It tells us how to correct the solutions to the unperturbed or undisturbed problem to approximately account for the [...]]]></description>
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<div dir="ltr"><span style="small;">by </span><span style="small;"><strong><span style="#e06666;">ANCELIE C. ROSALES</span></strong><strong></strong></p>
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<p></span><span style="small;">In quantum mechanics, the perturbation theory is a very important mathematical tool which is used to approximate physical quantities that describe complicated quantum systems based on our knowledge on the simpler ones. It tells us how to correct the solutions to the unperturbed or undisturbed problem to approximately account for the influence of the perturbation, as long as the perturbation is small compared to the unperturbed Hamiltonian.</span></div>
<p>The perturbation theory is best applied in the determination of the approximate correction to the energy levels and eigenstates after a certain perturbation is introduced to a real quantum system. To understand this deeply, let us look at this example.</p>
</div>
<div dir="ltr"><span style="small;">Consider a charged particle in the one-dimensional harmonic oscillator potential.  Suppose we turn on a weak electric field <em>E</em> so that the potential energy is shifted by an amount <em>H&#8217; = &#8211; qEx</em>.</p>
<p>a) Show that there is no first-order change in the energy levels and calculate the second-order correction.</p>
<p><strong>Solutions:</strong></p>
<p><span> </span><span> The first-order change in the energy levels with this given perturbation, <em>H&#8217; = -qEx</em> , is found using the fundamental result of the first-order perturbation theory which states that <em>the change in energy is just the average value of the perturbation Hamiltonian in the unperturbed states:</em></span></p>
<p><span style="small;"><img class="alignleft" src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn1.gif" alt="" /></span></p>
<p></span>.</p>
<p>Substituting the given perturbation into the equation, we get</p>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn2.gif" alt="" /><br />
where <em>n</em> is the n<sup>th</sup> eigenfunction. Employing the ladder operators (raising and lowering operators, <em>a<sub>+</sub></em> &amp; <em>a<sub>-</sub></em>, respectively) on <em>x</em> as in the equation,</p>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn3.gif" alt="" /></p>
<p><span style="small;">and we get the inner product </span></p>
</div>
<div dir="ltr"><span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn4.gif" alt="" /><br />
</span><span></p>
<div style="auto;">
<div><span style="small;">which can be written further as</span></div>
<div><span style="small;"> <img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn5.gif" alt="" width="336" height="43" />.<br />
</span></div>
<div>We recall that it was shown in the <a href="http://www.quantumsciencephilippines.com/99/properties-of-quantum-oscillators-1/">properties of quantum oscillators</a> that</div>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn6.gif" alt="" />and</p>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn7.gif" alt="" /></p>
<div><span style="small;"> and substituting these to our equation , we then get<br />
</span></div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn8.gif" alt="" />.</p>
<div><span style="small;"> We also have the relation that</span></div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn9.gif" alt="" />.</p>
<div><span style="small;">Since m = n+1 (<em>not equal to n</em>), then we now have</span></div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn10.gif" alt="" /></p>
</div>
<div style="auto;">
<div><span style="small;">so,<br />
</span></div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn11.gif" alt="" /></p>
</div>
<div><span style="small;">Finally, </span></p>
<div style="auto;"><span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn12.gif" alt="" />.</span></div>
<div><span style="small;">Thus, <strong>the first-order correction is indeed equal to 0.</strong></span></div>
<div><strong><br />
</strong>For the second-order correction, it is found using the fundamental equation of the second order perturbation theory which is</div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn13.gif" alt="" /></p>
<div><span style="small;">where </span></p>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn14.gif" alt="" />.</div>
<div><span style="small;">Following the same procedure as in getting the first-order correction in simplifying the numerator of the equation, that is, using the raising and lowering operators, we get<br />
</span></div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn15.gif" alt="" /></p>
<div><span style="small;">and simplifying, we now have</span></div>
<div><span style="small;"> <img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn16.gif" alt="" />.<br />
</span></div>
<div>
<div><span style="small;">With the delta function, it is important to note that</span></div>
<div><span style="small;"> </span> <img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn17.gif" alt="" />,<span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn18.gif" alt="" /></span></div>
</div>
<p><span style="small;"> and the above equation becomes</span></p>
<div style="auto;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn19.gif" alt="" />.</p>
<div>Substituting this to our fundamental equation, it becomes</div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn20.gif" alt="" /></p>
</div>
<div>and for a harmonic oscillator,</div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn21.gif" alt="" /></p>
</div>
<p>and</p>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn22.gif" alt="" />.</div>
<p>Then, our second-order equation becomes</p>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn23.gif" alt="" />.</div>
<div>Simplifying the numerator, we now have</div>
<div><span style="small;"></p>
<div style="center;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn24.gif" alt="" />.</div>
<p>It is important to note that</p>
<p></span></p>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn25.gif" alt="" /></p>
<div><span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn26.gif" alt="" /></p>
<div><span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn27.gif" alt="" /> </span></div>
<div><span style="small;">So, now we have the equation,<br />
</span></div>
<div>
<div><span style="small;"></p>
<div style="center;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn28.gif" alt="" />.</div>
<p>Finally,</p>
<div style="center;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn29.gif" alt="" />.</div>
<p></span></p>
<div>
<div><span style="small;">This is the <strong>second-order correction to the energy levels.</strong></span></div>
<div>
<div><span style="small;"><br />
b) The Schrödinger equation (SE) can be solved exactly in this case by a change of variables. </span><span style="small;">Find the exact energies and show that they are consistent with the perturbation theory approximation.</span></div>
<p><strong>Solutions:</strong></p>
<p>The Schrödinger equation for this potential is:</p>
<div style="auto;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn30.gif" alt="" /><span style="small;"><br />
</span></p>
<div><span style="small;"><br />
By change of variables, we let </span></div>
<p><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn31.gif" alt="" />.</p>
<div><span style="small;"> </span></p>
<div><span style="small;"> Considering first the potential part of the SE and changing the variables, we have<br />
</span></p>
<div>
<div>
<div>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn32.gif" alt="" />.</div>
<p><span style="small;">Thus, substituting this to our SE, it becomes,</span></p>
<div><span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn33.gif" alt="" /><br />
and rearranging terms, we get<br />
</span></p>
<div><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn34.gif" alt="" /><span style="small;"><br />
which is the SE for simple harmonic oscillator in the variable x&#8217;.<br />
We know that,<br />
</span></p>
<div><span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn35.gif" alt="" /></span></div>
<div><span style="small;">and finally </span></p>
<div><span style="small;"><img src="http://www.quantumsciencephilippines.com/images/ancelie/perturbation-theory-eqn36.gif" alt="" />.</span></div>
</div>
<p><span style="small;">In the above equation, the second term is the second order correction to the energy level and since we found that the first order correction is zero, thus <strong>this solution is consistent with the perturbation theory approximation.</strong></span></p>
<p>About the author:</p>
<p><span style="#e06666;"><strong>Ann </strong></span>finished her BS Physics degree at MSU main campus in Marawi City and is pursuing now a graduate degree at MSU-IIT, Iligan City. She is into performing experiments in Material Science and hopes to become one of the experimental physicists of the country someday.</p>
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		<title>Properties of Quantum Oscillators 1</title>
		<link>http://www.quantumsciencephilippines.com/99/properties-of-quantum-oscillators-1/</link>
		<comments>http://www.quantumsciencephilippines.com/99/properties-of-quantum-oscillators-1/#comments</comments>
		<pubDate>Fri, 03 Apr 2009 09:11:32 +0000</pubDate>
		<dc:creator>simonburgos</dc:creator>
				<category><![CDATA[Quantum Oscillators]]></category>
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		<category><![CDATA[Quantum Oscillator Hamiltonian]]></category>
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		<description><![CDATA[by SIMON JUDE BURGOS





In this post we investigate the properties of a quantum oscillator by using an algebraic tool in quantum mechanics called &#8216;ladder operators&#8217;. Using the ladder operator it becomes easy to find the following properties for a quantum oscillator in a given energy level:  the average position and momentum and the square of [...]]]></description>
			<content:encoded><![CDATA[<p><strong><span style="#800000;">by SIMON JUDE BURGOS</span></strong></p>
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<p>In this post we investigate the properties of a quantum oscillator by using an algebraic tool in quantum mechanics called &#8216;ladder operators&#8217;. Using the ladder operator it becomes easy to find the following properties for a quantum oscillator in a given energy level:  the average position and momentum and the square of these values as well as the average kinetic energy of a simple harmonic oscillator. In formal notation, we are looking for the following respective quantities: <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_xhat.gif" alt="" />, <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_phat.gif" alt="" />, <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_xhatsquared.gif" alt="" />, <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_phatsquared.gif" alt="" /> and <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_t.gif" alt="" />.</p>
<p><strong>Some discussion about ladder operators</strong></p>
<p>We begin by introducing the so-called ladder operators. There are two types: the raising operator, symbolized by <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_a1.gif" alt="" />, and the lowering operator, symbolized by <img style="middle;" src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_a.gif" alt="" />.  For reasons that will be evident later, the two are also called creation and annihilation operators respectively.</p>
<p>The ladder operators come from the roots of the Hamiltonian for a simple harmonic oscillator. The Hamiltonian is given by<br />
<img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/04/harmonicoscillatorqhamiltoniannew.gif" alt="" /><br />
which can be rewritten as</p>
<p><img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.qHamiltonian1.gif" alt="" /><br />
We then take the roots or factors of the expression inside the brackets. We should note however that we are dealing here with operators which do not commute. Simple algebraic factoring yields two roots:<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.Hroots0.gif" alt="" /><br />
To be clear, we rewrite the two roots separately below as</p>
<p><img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_raisingop.gif" alt="" /><br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_loweringop.gif" alt="" /><br />
where the momentum operator  is given by</p>
<p><img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.poperator.gif" alt="" /></p>
<p>To be able to find the expectation values of <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_xhat.gif" alt="" /> (position operator) , <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_phat.gif" alt="" /> (momentum operator) and <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_t.gif" alt="" /> (kinetic energy),  we express the position operator and momentum operator in terms of the ladder operators <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_a1.gif" alt="" /> and <img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_a.gif" alt="" /> . We add the two roots in order to get the expression for the position operator in terms of the ladder operators as<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_xHat.gif" alt="" /><br />
and then by subtracting the lowering from the raising operator gives the expression for the momentum operator as<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_pHat.gif" alt="" /></p>
<p>Now we consider the product of the two ladder operators. Since operators do not commute there are different results when we change the order when multiplying both operators:<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.a-a+.gif" alt="" /><br />
from which we derive the expression for the Hamiltonian as<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.Ha-a+.gif" alt="" />.<br />
The term in the braces is just the dimensionless Hamiltonian operator which is more convenient for our purposes:<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.Hhata-a+.gif" alt="" /><br />
This Hamiltonian operator can be expressed differently by multiplying the ladder operators in a different order. Then we get<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.Ha+a-.gif" alt="" /><br />
and its dimensionless counterpart is just<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.Hhata+a-.gif" alt="" /><br />
The Schroedinger eigenvalue equation for a simple harmonic oscillator will then yield<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.SEeigenvalueprob.gif" alt="" /><br />
hence it follows that<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.SEeigenvalueprobHhat.gif" alt="" /><br />
Now we can operate these ladder operators to  and see how the eigenvalues behave. We write down the action of the lowering operator as<br />
<img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/04/harmonicoscillatorladderopeffect1new.gif" alt="" />.<br />
Its adjoint is given by<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.ladderopeffect2.gif" alt="" /><br />
Multiplying the latter 2 equations gives us<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.ladderopeffect3.gif" alt="" /><br />
since  is the eigenfunction is normalized and  is given, then<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.ladderopeffect4.gif" alt="" /><br />
we finally arrive at the result that for the raising operator we have<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.ladderopeffect4a+.gif" alt="" /><br />
And also for lowering operator the result is<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator.ladderopeffect4a-.gif" alt="" />.</p>
<p>When using ladder operators it is imporatnt to note that orthogonality condition must be satisfied. The orthogonality condition  is given by,</p>
<p style="center;"><img class="aligncenter" src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_prob3_eqn12_orthogonality condition.gif" alt="" /></p>
<p style="center;"><strong>Finding the properties of a quantum oscillator</strong></p>
<p>Using the preceding results, we can now find the desired solutions to the problem initially given at the top of this post; which are<br />
a. In finding <a href="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_xhat.gif"><img class="alignnone size-medium wp-image-105" src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_xhat.gif" alt="" width="42" height="12" /></a>, we proceed as follows using the derived expression for the position operator in terms of the ladder operators. We note that <img class="alignnone size-medium wp-image-220" src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/03/x-expectationequiv.gif" alt="" width="95" height="17" /> where &lt;n| is any eigenvector. So we write,</p>
<p><img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_prob1_solution_a.gif" alt="" /></p>
<p>b. we can find <a href="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_phat.gif"><img class="alignnone size-medium wp-image-101" src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_phat.gif" alt="" width="41" height="15" /></a> in the same manner<br />
<img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_prob1_solution_b.gif" alt="" /></p>
<p>c. Finding <img class="alignnone size-medium wp-image-106" style="underline;" src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_xhatsquared.gif" alt="" width="49" height="15" /> involves a similar algebraic procedure</p>
<p><img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/04/harmonicoscillator_prob1_c1.gif" alt="" /><br />
d. We repeat the same algebraic procedure in finding for <a href="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_phatsquared.gif"><img class="alignnone size-medium wp-image-102" src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_phatsquared.gif" alt="" width="48" height="18" /></a>.</p>
<p><img src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/04/harmonicoscillator_prob1_d.gif" alt="" /><br />
e. Finally we can derive the expectation value for the kinetic energy, &lt;<strong>T</strong>&gt; in a straightforward way as</p>
<p><img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_prob1_solution_e.gif" alt="" />.</p>
<p><strong>Relation to Heisenberg&#8217;s Uncertainty Principle</strong></p>
<p>The quantum oscillator we have described above obeys the Heisenberg uncertainty principle.</p>
<p style="center;"><img class="aligncenter" src="http://www.quantumsciencephilippines.com/wp-content/uploads/2009/02/harmonicoscillator_uncertaintyprob.gif" alt="" /></p>
<p>We use the results from <strong>a</strong>) to <strong>d</strong>) above in proving these statements.</p>
<p><span> Using the above results, it is easy to see that<br />
</span></p>
<p><img src="http://www.quantumsciencephilippines.com/images/HarmonicOscillator_prob1_solution_sigmaxsigmapProof.gif" alt="" /></p>
<p>We thus have seen that the quantum harmonic oscillator satisfies the Heisenberg uncertainty principle.</p>
<p>About the Author:</p>
<p><strong>SIMON JUDE BURGOS </strong>is a graduate student in Physics at the Mindanao State University-Iligan Institute of Technology (MSU-IIT) in Mindanao, Philippines. He goals to work in research facilities in the field of medical physics. He will be finishing his masters degree soon and hope to go on to Ph.D. physics research in the near future.</p>

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